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Low-density polyethylene (LDPE) is a thermoplastic
made from petroleum. It was the first grade of polyethylene,
produced in 1933 by Imperial Chemical Industries (ICI) using a high
pressure process via free radical polymerization. Its manufacture
employs the same method today. LDPE is commonly recycled[citation
needed] and has the number "4" as its recycling symbol. Despite
competition from more modern polymers, LDPE continues to be an
important plastic grade. In 2009 the worldwide LDPE market reached a
volume of 22.2 billion US-Dollars (15.9 billion Euro).
Properties
LDPE is defined by a density range of 0.910–0.940 g/cm³. It is not
reactive at room temperatures, except by strong oxidizing agents,
and some solvents cause swelling. It can withstand temperatures of
80 °C continuously and 95 °C for a short time. Made in translucent
or opaque variations, it is quite flexible, and tough but
breakable.[citation needed]
LDPE has more branching (on about 2% of the carbon atoms) than HDPE,
so its intermolecular forces (instantaneous-dipole induced-dipole
attraction) are weaker, its tensile strength is lower, and its
resilience is higher. Also, since its molecules are less tightly
packed and less crystalline because of the side branches, its
density is lower. LDPE contains the chemical elements carbon and
hydrogen.
Chemical resistance
Excellent resistance (no attack) to dilute and
concentrated acids, alcohols, bases and esters
Good resistance (minor attack) to aldehydes, ketones and vegetable
oils
Limited resistance (moderate attack suitable for short-term use
only) to aliphatic and aromatic hydrocarbons, mineral oils, and
oxidizing agents
Poor resistance, and not recommended for use with Halogenated
hydrocarbons.
Applications
LDPE is widely used for manufacturing various containers, dispensing
bottles, wash bottles, tubing, plastic bags for computer components,
and various molded laboratory equipment. Its most common use is in
plastic bags. Other products made from it include:
Trays and general purpose containers
Food storage and laboratory containers
Corrosion-resistant work surfaces
Parts that need to be weldable and machinable
Parts that require flexibility, for which it serves very well
Very soft and pliable parts
Six pack rings
Juice and milk cartons, whose "cardboard" is actually liquid
packaging board, a laminate of paperboard and LDPE (as the
water-proof inner and outer layer), and often with of a layer of
aluminum foil (thus becoming aseptic packaging).
Parts of computer hardware, such as hard disk drives, screen cards,
and optical disc drives
Playground slides
Plastic wraps